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Thermally Activated Delayed Fluorescence Organic Light-Emitting Diodes (TADF-OLEDs) comprehensively introduces the history of TADF, along with a review of fundamental concepts. Then, TADF emitters with different colors, such as blue, green, red and NIR as well as white OLEDs are discussed in detail. Other sections cover exciplex-type TADF materials, emerging application of TADF emitters as a host in OLEDs, and applications of TADF materials in organic lasers and biosensing. List of contributors. Brief history of OLEDs and TADF materials for OLEDs. Abstract. Introduction. Early history of OLEDs. Early history of TADF materials for OLEDs. Summary and outlook. References. Fundamental theories of TADF. Abstract. Vertical and 0–0 energies. The singlet–triplet energy splitting (ΔEST). Fluorescence radiation rates. Nonradiative transition rates. TADF rates. References. Aggregation-induced delayed fluorescence. Abstract. Introduction. Development of AIDF luminogens. Conclusions and outlook. Reference. Highly efficient and stable blue thermally activated delayed fluorescent organic light-emitting diodes. Abstract. Introduction. Achieving blue OLEDs: the potential strategies. Design paradigm for blue TADF materials. Blue TADF emitters with high horizontally oriented transition dipoles. Blue TADF emitters with ultrahigh color purity. Efficient nondoped blue TADF-OLEDs. Stability of blue TADF materials and devices. Stable blue TADF emitters. Designing stable host materials for blue TADF emitters. Outlook and prospect. References. Orange, red, and near-infrared thermally activated delayed fluorescent emitters. Abstract. Introduction. Molecular design principles. TADF emitters. Outlook. References. WOLEDs using TADF dopants. Abstract. Introduction. WOLEDs using TADF dopants. WOLEDs based on TADF-sensitized fluorescence. WOLEDs based on all TADF dopants. Hybrid WOLEDs based on TADF dopants. Hybrid WOLEDs based on monomolecular TADF. Challenges and outlooks. References. OLEDs using molecular TADF materials as hosts. Abstract. Introduction. TADF sensitized conventional fluorescent dopants. TADF sensitized phosphorescent dopants. TADF-sensitized TADF dopants. Exciplexes sensitized conventional fluorescent dopants. Exciplexes sensitized phosphorescent dopants. Exciplex hosts with TADF dopants. References. Thermally activated delayed fluorescence exciplexes in organic light-emitting diodes. Abstract. Introduction. Formation of TADF exciplexes. Development of TADF exciplex emitters. Development of high-performance exciplex hosts. Conclusions and outlook. References. Thermally activated delayed fluorescent materials for other applications. Abstract. Introduction. Leverage of singlet exciton. Leverage of long exciton lifetime. Leverage of triplet exciton. Conclusion. References. Status and future outlook of TADF materials and OLEDs. Abstract. Recent progress of TADF materials in academia and industry. Mechanism. Materials and devices. Other applications. References. Index